Electrodeposition of Bi-Sb-Te Alloys by Pulse Electrolysis in AlCl3-NaCl-KCl Molten Salt

被引：3

作者：

Ueda, Mikito ^{[1
]}

Tsuchiya, Shoh ^{[1
]}

Ohtsuka, Toshiaki ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Sapporo, Hokkaido 0608628, Japan

来源：

ELECTROCHEMISTRY | 2009年 / 77卷 / 08期

关键词：

Thermoelectric Material; Bi-Sb-Te Alloy; Molten Salt;

D O I：

10.5796/electrochemistry.77.659

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrodeposition of Sb-Bi-Te alloy in AlCl3-NaCl-KCl molten salt containing SbCl3, BiCl3, and TeCl4, at 423 K was carried out under constant potential control and potential pulse control in the melt. The electrodeposition results show that the SbCl3 concentration is effective to control the composition of Bi-Sb-Te ternary alloy. The electrodeposited Bi0.5Sb1.5Te3 by pulse electrolysis with frequency = 100 Hz and D. R. (Duty Ratio)= 75%, had good crystallinity and the preferential orientation of the electrodeposit was the (110) plane in this electrodeposition experiments. The electrodeposit had homogeneous disk-like granules. The power factor of the electrodeposit was calculated as 3 x 10(-5) Wm(-1) K-2 from the Seebeck coefficient and the electrical conductivity.

引用

页码：659 / 662

页数：4

共 7 条

[1] Electrodeposition of Sb, Bi, Te, and their alloys in AlCl3-NaCl-KCl molten salt [J].