A novel rearrangement reaction of β-diazo-α-ketoacetals

被引：10

作者：

Erhunmwunse, Marvis O. ^{[1
,2
]}

Steel, Patrick G. ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England

[2] Univ Benin, Dept Chem, Fac Phys Sci, Benin 1154, Nigeria

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 26期

关键词：

Rhodium carbenoid; Wolff rearrangement; Ketal; Lactone; Ketene; C-H INSERTION; DIAZOCARBONYL COMPOUNDS; RHODIUM CARBENOIDS; ORGANIC-SYNTHESIS; PRODUCTS;

D O I：

10.1016/j.tetlet.2009.03.025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of pyruvate ketal-derived diazoacetoacetates or vinyldiazoketones with rhodium(II) complexes at elevated temperatures results in an Unusual skeletal rearrangement to afford eight-membered ring lactones. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：3568 / 3570

页数：3

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