Superior capacitive performance of active carbons derived from Enteromorpha prolifera

被引:154
作者
Gao, Xiuli [1 ]
Xing, Wei [1 ]
Zhou, Jin [2 ]
Wang, Guiqiang [2 ]
Zhuo, Shuping [2 ]
Liu, Zhen [1 ]
Xue, Qingzhong [1 ]
Yan, Zifeng [1 ]
机构
[1] China Univ Petr, Sch Sci, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China
[2] Shandong Univ Technol, Sch Chem Engn, Zibo 255049, Peoples R China
基金
中国国家自然科学基金;
关键词
Biomass; enteromorpha prolifera; active carbon; KOH activation; supercapacitor; DOUBLE-LAYER CAPACITORS; POROUS CARBON; SURFACE-AREA; NANOPOROUS CARBON; CO2; CAPTURE; HIGH-ENERGY; PORE-SIZE; SUPERCAPACITORS; ACTIVATION; ELECTRODES;
D O I
10.1016/j.electacta.2014.04.101
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Enteromorpha prolifera (E.prolifera), an ocean biomass, was used as raw materials to prepare active carbons by a two-step strategy (pre-carbonization followed by chemical activation). The as-prepared active carbons have been characterized by a variety of means such as N-2 adsorption, field emission scanning electron microscope, transmission electron microscope, Raman spectroscopy. The results showed that the carbons have large surface area and developed porosity with micro-meso hierarchical pore texture. As evidenced by electrochemical measurements, the specific capacitance of the carbons can reach up to 296 F g(-1). More importantly, the carbons can maintain a high capacitance of up to 152 F g(-1) at a very high current density of 30 A g(-1), highlighting the promise of the carbons for high power applications. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:459 / 466
页数:8
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