Pd(II) Catalyzed Copolymerization of Styrene and CO in Quaternary Ammonium Ionic Liquids

被引：1
|
作者：
Tian, Jing [1 ]
Guo, Jin-Tang [1 ]
Zhu, Cheng-Cai [1 ]
Zhang, Xin [1 ]
Xu, Yong-Shen [1 ]
机构：
[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
来源：
MACROMOLECULAR RESEARCH | 2009年 / 17卷 / 03期
关键词：
poly(1-oxo-2-phenyltrimethylene); ionic liquids; palladium catalyst; carbon monoxide; catalytic activity; CARBON-MONOXIDE; ALTERNATING COPOLYMERIZATION; POLYMERIZATION; COMPLEXES; LIGANDS;
D O I：
10.1007/BF03218670
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(1-oxo-2-phenyltrimethylene) was synthesized by palladium-catalyzed copolymerization of styrene and carbon monoxide in quaternary ammonium ionic liquids. The [Pd(bipy)(2)][PF6](2) compound had relatively more catalytic activity than [Pd(bipy)(2)][BF4](2) in ionic liquids. The catalytic activity of palladium (II) composite catalyst was superior to the catalyst formed in situ from palladium acetate, 2,2-bipyridyl, and X- (X-=PF6-, BF4-) in ionic liquids. The effects of the volume of ionic liquids, reaction time and benzoquinone content on the copolymerization were also described.
引用
收藏
页码：144 / 148
页数：5
相关论文
共 50 条
  • [1] Pd(II) catalyzed copolymerization of styrene and CO in quaternary ammonium ionic liquids
    Jing Tian
    Jin-Tang Guo
    Cheng-Cai Zhu
    Xin Zhang
    Yong-Shen Xu
    Macromolecular Research, 2009, 17 : 144 - 148
  • [2] Promoting the sulfuric acid catalyzed isobutane alkylation by quaternary ammonium ionic liquids
    Cao, Piao
    Yuan, Yuan
    Huang, Chizhou
    Sun, Weizhen
    Zhao, Ling
    AICHE JOURNAL, 2020, 66 (08)
  • [3] Syndiotactic CO/Styrene copolymerization catalyzed by α-diimine Pd(II) complexes:: Regio- and stereochemical control
    Carfagna, C
    Gatti, G
    Martini, D
    Pettinari, C
    ORGANOMETALLICS, 2001, 20 (11) : 2175 - 2182
  • [4] Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts
    Klingshirn, MA
    Broker, GA
    Holbrey, JD
    Shaughnessy, KH
    Rogers, RD
    CHEMICAL COMMUNICATIONS, 2002, (13) : 1394 - 1395
  • [5] Selective oxidation of styrene catalyzed by Pd/carboxyl-appended ionic liquids
    Li Xuehui
    Geng Weiguo
    Wang Furong
    Wang Lefu
    CHINESE JOURNAL OF CATALYSIS, 2006, 27 (11) : 943 - 945
  • [6] Base stable quaternary ammonium ionic liquids
    Lethesh, Kallidanthiyil Chellappan
    Dehaen, Wim
    Binnemans, Koen
    RSC ADVANCES, 2014, 4 (09) : 4472 - 4477
  • [7] Enzymatic Polymerization of Phenols Catalyzed by Chloroperoxidase in the Presence of Ionic Liquids/Quaternary Ammonium Salts
    Wang Shengjie
    Liu Lixia
    Jiang Yucheng
    Hu Mancheng
    Li Shuni
    Zhai Quanguo
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2016, 37 (09): : 1733 - 1739
  • [8] Palladium catalyzed co/alkene copolymerization in Room Temperature Ionic Liquids.
    Rogers, RD
    Klingshirn, MA
    Broker, GA
    Holbrey, JD
    Shaughnessy, KH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U510 - U510
  • [9] Ionic Liquid-Complex Pd/C System as Catalyst for Copolymerization of CO and Styrene
    王海霞
    郭锦棠
    胡光
    冯亚凯
    武瑞涛
    Transactions of Tianjin University, 2014, (01) : 48 - 53
  • [10] Ionic Liquid-Complex Pd/C System as Catalyst for Copolymerization of CO and Styrene
    王海霞
    郭锦棠
    胡光
    冯亚凯
    武瑞涛
    Transactions of Tianjin University, 2014, 20 (01) : 48 - 53
12345