Pd(II) Catalyzed Copolymerization of Styrene and CO in Quaternary Ammonium Ionic Liquids

被引：1
作者：
Tian, Jing [1 ]
Guo, Jin-Tang [1 ]
Zhu, Cheng-Cai [1 ]
Zhang, Xin [1 ]
Xu, Yong-Shen [1 ]
机构：
[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
来源：
MACROMOLECULAR RESEARCH | 2009年 / 17卷 / 03期
关键词：
poly(1-oxo-2-phenyltrimethylene); ionic liquids; palladium catalyst; carbon monoxide; catalytic activity; CARBON-MONOXIDE; ALTERNATING COPOLYMERIZATION; POLYMERIZATION; COMPLEXES; LIGANDS;
D O I：
10.1007/BF03218670
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(1-oxo-2-phenyltrimethylene) was synthesized by palladium-catalyzed copolymerization of styrene and carbon monoxide in quaternary ammonium ionic liquids. The [Pd(bipy)(2)][PF6](2) compound had relatively more catalytic activity than [Pd(bipy)(2)][BF4](2) in ionic liquids. The catalytic activity of palladium (II) composite catalyst was superior to the catalyst formed in situ from palladium acetate, 2,2-bipyridyl, and X- (X-=PF6-, BF4-) in ionic liquids. The effects of the volume of ionic liquids, reaction time and benzoquinone content on the copolymerization were also described.
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收藏
页码：144 / 148
页数：5
相关论文
共 18 条
  • [1] Application of molten salts in hydroalkoxycarbonylation of styrene
    Balázs, A
    Benedek, C
    Torös, S
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 244 (1-2) : 105 - 109
  • [2] Belov G.P., 2004, Russ. Chem. Rev, V73, P267, DOI [DOI 10.1070/RC2004V073N03ABEH000840, 10.1039/a903411k, DOI 10.1039/A903411K]
  • [3] Alkylation of naphthalene using three different ionic liquids
    Blanco, Carlos Gutierrez
    Banciella, Dolores Casal
    Azpiroz, M. Dolores Gonzalez
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 253 (1-2) : 203 - 206
  • [4] Copper(I) mediated living radical polymerisation in an ionic liquid
    Carmichael, AJ
    Haddleton, DM
    Bon, SAF
    Seddon, KR
    [J]. CHEMICAL COMMUNICATIONS, 2000, (14) : 1237 - 1238
  • [5] Physicochemical properties and solubility of alkyl-(2-hydroxyethyl)-dimethylammonium bromide
    Domanska, U
    Bogel-Lukasik, R
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (24) : 12124 - 12132
  • [6] Palladium-catalyzed alternating copolymerization of alkenes and carbon monoxide
    Drent, E
    Budzelaar, PHM
    [J]. CHEMICAL REVIEWS, 1996, 96 (02) : 663 - 681
  • [7] The oxo-synthesis catalyzed by cationic palladium complexes, selectivity control by neutral ligand and anion
    Drent, E
    Budzelaar, PHM
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 593 : 211 - 225
  • [8] The role of nitrogen-donor ligands in the palladium-catalyzed polyketones synthesis
    Durand, J
    Milani, B
    [J]. COORDINATION CHEMISTRY REVIEWS, 2006, 250 (3-4) : 542 - 560
  • [9] Palladium-promoted carbon monoxide/ethylene/styrene terpolymerization reaction: Throwing light on the different reactivity of the two alkenes
    Durand, Jerome
    Scarel, Alessandro
    Milani, Barbara
    Seraglia, Roberta
    Gladiali, Serafino
    Carfagna, Carla
    Binotti, Barbara
    [J]. HELVETICA CHIMICA ACTA, 2006, 89 (08) : 1752 - 1771
  • [10] Alternating copolymerisation of styrene and carbon monoxide in ionic liquids
    Hardacre, C
    Holbrey, JD
    Katdare, SP
    Seddon, KR
    [J]. GREEN CHEMISTRY, 2002, 4 (02) : 143 - 146
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