LANTHANUM TRIFLATE-CATALYZED RAPID OXIDATION OF SECONDARY ALCOHOLS USING HYDROGEN PEROXIDE UREA ADDUCT ( UHP) IN IONIC LIQUID

被引：4

作者：

Saluja, Pooja ^{[1
]}

Magoo, Devanshi ^{[1
]}

Khurana, Jitender M. ^{[1
]}

机构：

[1] Univ Delhi, Dept Chem, Delhi 110007, India

来源：

SYNTHETIC COMMUNICATIONS | 2014年 / 44卷 / 06期

关键词：

Ionic liquid; ketones; lanthanum triflate; oxidation; secondary alcohols; UHP; SOLVENT-FREE OXIDATION; CARBONYL-COMPOUNDS; 1,2-DIKETONES; HYDROBENZOINS; BENZOINS; SALTS;

D O I：

10.1080/00397911.2013.831904

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient and efficient protocol for the oxidation of secondary hydroxyl group to ketone using hydrogen peroxide-urea adduct and catalytic (CF3SO3)(3)La in ionic liquid has been developed. A number of 1,2-diols, -hydroxyketones, and other aromatic and aliphatic secondary alcohols have been successfully oxidized to the corresponding ketones using this protocol in good yields and short reaction times. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource(s): Full experimental and spectral details.]

引用

页码：800 / 806

页数：7

共 22 条

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