A successive-reaction nanoreactor made of active molecularly imprinted polymer containing Ag nanoparticles

被引：25

作者：

Li, Songjun ^{[1
]}

Luo, Yiyun ^{[1
]}

Whitcombe, Michael J. ^{[2
]}

Piletsky, Sergey A. ^{[2
]}

机构：

[1] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China

[2] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 47期

关键词：

SILVER NANOPARTICLES; SHELL; CATALYSIS; NETWORKS; CARBON; CORE;

D O I：

10.1039/c3ta13454g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A successive-reaction nanoreactor made of a unique molecularly imprinted polymer containing Ag nanoparticles is reported. This molecularly imprinted polymer was fabricated using two well-coupled templates, i.e., 4-nitrophenyl acetate and 4-nitrophenol. The catalytic hydrolysis of the former by this nanoreactor led to the formation of the latter, which was further reduced by the nanoreactor to 4-aminophenol. Unlike reported nanoreactors, which usually promote one single reaction, this novel nanoreactor can run cascade reactions. The proposed integration of active molecularly imprinted polymers with metal nanoparticles opens a new opportunity for creating functional catalysts for complicated chemical processes.

引用

页码：15102 / 15109

页数：8

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