Anchoring molecular magnets on the Si(100) surface

被引：95
作者：
Condorelli, GG
Motta, A
Fragalà, IL
Giannazzo, F
Raineri, V
Caneschi, A
Gatteschi, D
机构：
[1] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy
[2] INSTM UdR Catania, I-95125 Catania, Italy
[3] CNR, IMM, Sez Catania, I-95121 Catania, Italy
[4] Univ Florence, Dipartimento Chim, I-50019 Sesto Fiorentino, Italy
[5] INSTM UdR Firenze, I-50019 Sesto Fiorentino, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 31期
关键词：
cluster compounds; monolayers; photoelectron spectroscopy; single-molecule magnets; surface chemistry;
D O I：
10.1002/anie.200453933
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrosilylation by H-terminated silicon of the double bond of methyl 10-undecenoate with formation of a robust Si-C bond is the first step in a three-step procedure (see scheme) for anchoring the single-molecule magnet (SMM) [Mn12O12(OAc)16(H2O)4] (1) on the Si(100) surface.
引用
收藏
页码：4081 / 4084
页数：4
相关论文
共 17 条
  • [1] BRIGGS D, 1995, PRACTICAL SURFACES A, V1, P440
  • [2] Multiple length scale patterning of single-molecule magnets
    Cavallini, M
    Biscarini, F
    Gomez-Segura, J
    Ruiz, D
    Veciana, J
    [J]. NANO LETTERS, 2003, 3 (11) : 1527 - 1530
  • [3] Toward a hybrid micro-nanoelectronics
    Cerofolini, GF
    Ferla, G
    [J]. JOURNAL OF NANOPARTICLE RESEARCH, 2002, 4 (03) : 185 - 191
  • [4] Functionalization of the (100) surface of hydrogen-terminated silicon via hydrosilation of 1-alkyne
    Cerofolini, GF
    Galati, C
    Reina, S
    Renna, L
    [J]. MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2003, 23 (1-2): : 253 - 257
  • [5] The early oxynitridation stages of hydrogen-terminated (100) silicon after exposure to N2:N2O.: III.: Initial conditions
    Cerofolini, GF
    Galati, C
    Lorenti, S
    Renna, L
    Viscuso, O
    Bongiorno, C
    Raineri, V
    Spinella, C
    Condorelli, GG
    Fragalà, IL
    Terrasi, A
    [J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2003, 77 (3-4): : 403 - 409
  • [6] CHRISTOU G, 2000, MAT RES B, V35, P66
  • [7] Direct observation of single-molecule magnets organized on gold surfaces
    Cornia, A
    Fabretti, AC
    Pacchioni, M
    Zobbi, L
    Bonacchi, D
    Caneschi, A
    Gatteschi, D
    Biagi, R
    Del Pennino, U
    De Renzi, V
    Gurevich, L
    Van der Zant, HSJ
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (14) : 1645 - 1648
  • [8] Cornia A., 2003, ANGEW CHEM, V115, P1683
  • [9] XPS STUDY OF MNO OXIDATION
    DICASTRO, V
    POLZONETTI, G
    [J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1989, 48 (1-2) : 117 - 123
  • [10] HIGH-SPIN MOLECULES - UNUSUAL MAGNETIC-SUSCEPTIBILITY RELAXATION EFFECTS IN [MN12O12(O(2)CET)(16)(H2O)(3)] (S=9) AND THE ONE-ELECTRON REDUCTION PRODUCT (PPH4)[MN12O12(O(2)CET)(16)(H2O)(4)] (S=19/2)
    EPPLEY, HJ
    TSAI, HL
    DEVRIES, N
    FOLTING, K
    CHRISTOU, G
    HENDRICKSON, DN
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) : 301 - 317
12