Effects of Yb codoping on photoluminescence of Er3+ ions at room temperature in SiO2 films thermally grown on silicon are investigated. We demonstrate that for an excitation wavelength of 488 nm Yb ions act as efficient sensitizers of the I-4(13/2)-I-4(15/2) emission of Er3+ ions. We have found that for the tired dose of Yb the Er3+ intensity is directly proportional to the Er concentration. Models of the mechanisms responsible for sensitization are discussed. It is shown that the Yb/Er concentration ratio of 0.5-2 is optimum for the dopant densities of 2-4x10(20) cm(-3). (C) 2000 Elsevier Science S.A. Ail rights reserved.