Anticorrosion properties of Ta-coated 316L stainless steel as bipolar plate material in proton exchange membrane fuel cells

被引:33
|
作者
Yu, Haijun [1 ]
Yang, Lijun [1 ]
Zhu, Lei [1 ]
Jian, Xuyu [1 ]
Wang, Zhong [1 ]
Jiang, Lijun [1 ]
机构
[1] Beijing Gen Res Inst Nonferrous Met, Dept Energy Mat & Technol, Beijing 100088, Peoples R China
关键词
Proton exchange membrane fuel cell (PEMFC); Bipolar plate; 316L stainless steel (SS316L); Tantalum (Ta); Corrosion current density; PERFORMANCE; COATINGS; TIN; PEMFCS; STACK; COST;
D O I
10.1016/j.jpowsour.2009.02.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In order to reduce the Cost, volume and weight of the bipolar plates used in the proton exchange membrane fuel cells (PEMFC), more attention is being paid to metallic materials, among which 316L stainless steel (SS316L) is quite attractive. In this study, metallic Ta is deposited on SS316L using physical vapor deposition (PVD) to enhance file corrosion resistance of the bipolar plates. Simulative working environment of PEMFC is applied for testing the corrosion property Of uncoated and Ta-coated SS316L. X-ray diffraction (XRD). scanning electron microscopy (SEM) and electrochemical methods (potentiodynamic and potentiostatic polarization) are also Used for analyzing characteristics of uncoated and Ta-coated SS316L. Results show chat, Ta-coated SS316L has significantly better anticorrosion property than that of uncoated SS316L. with, corrosion current densities Of uncoated SS316L being 44.61 mu A cm (2) versus 9.25 mu A cm (2) for Ta-coated SS316L a decrease of about 5 times. Moreover, corrosion current densities of Ta-coated SS316L in both simulative anode (purged with H(2)) and cathode (Purged with air) conditions ate smaller than those of uncoated SS316L. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:495 / 500
页数:6
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