Chemical Processes in Systems CuI(CuII)/L/[B12H12]2-/solv (L = bipy, phen; solv = CH3CN, DMF, and CH2I2)

被引：6

作者：

Kochneva, I. K. ^{[1
]}

Avdeeva, V. V. ^{[1
]}

Goeva, L. V. ^{[1
]}

Malinina, E. A. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 63卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

COMPLEXES; COPPER(I); REDOX;

D O I：

10.1134/S0036023618050066

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Processes proceeding in the Cu-I(Cu-II)/L/(L = bipy, phen) systems in the presence of the [B12H12](2-) anion, which has the lowest reduction ability among the boron cluster anions [B (n) H (n) ](2-) (n = 6, 10, 12), have been studied. It has been found that the preparation of Cu-I and heterovalent Cu-I/Cu-II complexes with azaheterocyclic ligands and the [B12H12](2-)anion requires the Cu-II reduction process to be initiated. To minimize the redox process in the Cu-I/L/[B12H12](2-) system, redox-active starting components have been added to the reaction system. Mono- and polynuclear copper complexes with various composition and structures have been isolated as a result of redox reactions proceeding in the Cu-I(Cu-II)/L/[B12H12](2-)/solv (L = bipy, phen; solv = CH3CN, DMF, CH2I2) systems.

引用

页码：591 / 596

页数：6

共 9 条

[1] Redox processes in the Cu/(&ITphen&IT)/[B12H12]2-/solv system: Selective preparation of copper(I), copper(II), and heterovalent copper(I/II) compounds
Malinina, Elena A.
Kochneva, Irina K.
Polyakova, Irina N.
Avdeeva, Varvara V.
Goeva, Lyudmila V.
Minin, Vadim V.
Ugolkova, Elena A.
Kuznetsov, Nikolai T.
INORGANICA CHIMICA ACTA, 2018, 477 : 284 - 291
[2] Synthesis and Structure of Mononuclear Copper(II) Complexes with Azaheterocyclic Ligands L (L = Bipy, BPA, and Phen) and Dodecahydro-closo-Dodecaborate Anion [B12H12]2-
Malinina, E. A.
Kochneva, I. K.
Avdeeva, V. V.
Goeva, L. V.
Kubasov, A. S.
Kuznetsov, N. T.
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[3] Synthesis and Crystal Structures of (HL)2[B10Cl10]•3CH3CN (L = Bipy, Phen)
Avdeeva, V. V.
Vologzhanina, A. V.
Nikiforova, S. E.
Buzanov, G. A.
Malinina, E. A.
Kuznetsov, N. T.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 68 (06) : 737 - 743
[4] Tuning the Structures of AsMo12 and AsW12 into Chiral Crystals by Introducing CH3CN and H2O
Wang, Youlin
Lu, Xiaoming
Min, Tao
Feng, Jun
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (3-4): : 724 - 727
[5] Structural diversity and spectral and thermal properties of the first alkaline earth metal tetracyanidoborates: [Mg(H2O)6][B(CN)4]2, [Mg(H2O)2]-[ B(CN)4]2, [Mg(DMF)6][B(CN)4]2, [Ca(H2O)3][B(CN)4]2, and [Ca(H2O)2(CH3CN)][B(CN)4]2
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Koeckerling, Martin
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DALTON TRANSACTIONS, 2014, 43 (19) : 7128 - 7138
[6] Ligand metathesis in copper(I) complex [Cu2(CH3CN)4[B10H10]] to form [Cu2L4[B10H10]] (L = Ph3P, 5Nphen)
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Malinina, Elena A.
Churakov, Andrei V.
Polyakova, Irina N.
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POLYHEDRON, 2019, 169 : 144 - 150
[7] Homoleptic silver-bis(pyridine) coordination polymers: [Ag(L1)2]•(PF6), [Ag(L1)2]•(SbF6), [Ag(L1)2]•BF4), [Ag(L2)]•(PF6), and [Ag(L3)1.5]•(CF3SO3)•(H2O)2 {L1 = (4-py)-CH=N-C10H6-N=CH-(4-py); L2 = (2-py)-CH=N-C10H6-N=CH-(2-PY); L3 = (3-py)-CH=N-C14H12-N=CH-(3-PY)}
Jang, Young Ok
Lee, Soon W.
POLYHEDRON, 2010, 29 (13) : 2731 - 2738
[8] Theoretical Insight into B-C Chemical Bonding in Closo-Borate [BnHn-1CH3]2- (n=6, 10, 12) and Monocarborane [CBnHnCH3]- (n=5, 9, 11) Anions
Klyukin, Ilya N.
Kolbunova, Anastasia, V
Novikov, Alexander S.
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Zhizhin, Konstantin Yu
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INORGANICS, 2022, 10 (11)
[9] High versatility of 3,4-dimethyl-1-phenyl-phosphole and 3-methyl-1-phenyl-phosphole as ligands in the reaction with [Re2(CO)8(CH3CN)2] and [Ru3(CO)12]: X-ray structures of [Re2(CO)7(η1:η2:η2-PhPC4H2Me2)], [Re2(CO)7(η1:η2:η2-PhPC4H3Me)] and [Ru2(CO)4(PhPC4H3Me)2]
Otero, Yomaira
Arce, Alejandro
De Sanctis, Ysaura
Machado, Ruben
Goite, Maria C.
Gonzalez, Teresa
Briceno, Alexander
INORGANICA CHIMICA ACTA, 2013, 404 : 77 - 81

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