Synthesis and structure of the cubane type [Fe2Sb(CO)5(η5-C5H5)]4 cluster

被引：6
|
作者：
Konchenko, SN
Virovets, AV
Apenina, SA
Tkachev, SV
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 11期
关键词：
crystal structures; iron complexes; antimony complexes; cubane complexes; cluster complexes;
D O I：
10.1016/S1387-7003(99)00142-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The [Fe2Sb(CO)(5)Cp](4) (Cp = eta(5)-C5H5) cluster has been obtained by the thermolysis of [Et4N] [{Fe(CO)(4)}(2)(Fe(CO)(2)Cp}SbI]. The structure of the [Fe2Sb(CO)(5)Cp](4). 2toluene solvate has been determined by X-ray analysis. The cluster contains the cubane [Fe4Sb4] core, Each Sb serves as a mu(4)-ligand between three iron atoms of the core and one of a terminal [Fe(CO)(2)Cp] group. (C) 1999 Published by Elsevier Science S.A. All rights reserved.
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页码：555 / 557
页数：3
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