Bio-oil production via co-pyrolysis of almond shell as biomass and high density polyethylene

被引：273

作者：

Onal, Eylem ^{[2
]}

Uzun, Basak Burcu ^{[1
]}

Putun, Ayse Eren ^{[1
]}

机构：

[1] Anadolu Univ, Dept Chem Engn, TR-26555 Eskisehir, Turkey

[2] Bilecik Seyh Edebali Univ, Fac Engn Chem & Proc Engn, Bilecik, Turkey

来源：

ENERGY CONVERSION AND MANAGEMENT | 2014年 / 78卷

关键词：

Bio oil; Co-pyrolysis; HDPE; Almond shell; SYNTHETIC-POLYMERS MIXTURES; WOOD BIOMASS; PART; POLYPROPYLENE; RESIDUE; TEMPERATURE; COPYROLYSIS;

D O I：

10.1016/j.enconman.2013.11.022

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Biomass from almond shell (aS) was co-pyrolyzed with high density polyethylene (HDPE) polymer to investigate the synergistic effects on the product yields and compositions. The pyrolysis temperature was selected as 500 C, based on results of TGA-DTG. Co-pyrolysis of HDPE-biomass mixtures were pyrolysed with various proportions such as 1:0, 1:1, 1:2,2:1 and 0:1. The yield of liquids produced during co-pyrolysis enhanced 23%, as the weight ratio of HDPE in the mixture was doubled. Obtained bin-oils were analyzed with using column chromatography, H-1 NMR, GC/MS, and FT-IR. According to analyses results, produced liquids by co-pyrolysis had higher carbon (26% higher) and hydrogen contents (78% higher), lower oxygen content (%86 less) with a higher heating value (38% higher) than those of biomass oil. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：704 / 710

页数：7

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