Noncatalytic Polycondensation of L-Lactic Acid under Microwave Irradiation

被引：11
|
作者：
Hirao, Koichi [1 ]
Masutani, Kazunari [1 ]
Ohara, Hitomi [1 ]
机构：
[1] Kyoto Inst Technol, R&D Ctr Biobased Mat, Sakyo Ku, Kyoto 6068585, Japan
来源：
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN | 2009年 / 42卷 / 06期
关键词：
Microwave Irradiation; Noncatalysts; Polycondensation; Poly(Lactic Acid); POLY(L-LACTIC ACID); CATALYSTS;
D O I：
10.1252/jcej.09we040
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Noncatalytic polycondensation of L-lactic acid under microwave irradiation is compared with that under conventional heating. Under microwave irradiation, higher molecular weights of poly(L-lactic acid) can be obtained comparing with under conventional heating. Though the racemization of L-lactate was induced, it can be lowered at higher vacuum. As a result, higher molecular weight poly(L-lactic acid), comparing with conventional heating without increasing racemization, was synthesized with microwave irradiation.
引用
收藏
页码：417 / 419
页数：3
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