A combined SAXS/WAXS/XAFS setup capable of observing concurrent changes across the nano-to-micrometer size range in inorganic solid crystallization processes

被引：85
作者：
Beale, Andrew M.
van der Eerden, Ad M. J.
Jacques, Simon D. M.
Leynaud, Olivier
O'Brien, Matthew G.
Meneau, Florian
Nikitenko, Sergei
Bras, Wim
Weckhuysen, Bert M.
机构：
[1] Univ Utrecht, NL-3584 CA Utrecht, Netherlands
[2] UCL, Dept Chem, London WC1H 0AJ, England
[3] ESRF, DUBBLE, F-38042 Grenoble, France
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 38期
关键词：
D O I：
10.1021/ja062580r
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel combined SAXS/WAXS/XAFS setup for studying the self-assembly processes occurring during the crystallization of porous materials, such as ZnAlPO-34, is described. In a single experiment, it has been possible to obtain congruent and time-resolved information on aggregation processes in the synthesis gel, the incorporation process of Zn2+ ions in the framework, and the formation of the crystalline material. Copyright © 2006 American Chemical Society.
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页码：12386 / 12387
页数：2
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