Electrodeposition of PEDOT-rGO film in aqueous solution for detection of acetaminophen in traditional medicaments

被引:32
作者
Cong Thanh Ly [1 ]
Chien Thang Phan [1 ]
Cam Nhung Vu [2 ]
Hoang Sinh Le [3 ]
Thi Tuyet Nguyen [1 ]
Dai Lam Tran [4 ]
Lan Anh Le [5 ]
Thi Thu Vu [2 ,6 ]
机构
[1] HUP, 15-17 Le Thanh Tong, Hanoi, Vietnam
[2] USTH, VAST, 18 Hoang Quoc Viet, Hanoi, Vietnam
[3] DTU, 03 Quang Trung, Da Nang, Vietnam
[4] VAST, ITT, 18 Hoang Quoc Viet, Hanoi, Vietnam
[5] Vietnam Russia Trop Ctr, Inst Biomed, 63 Nguyen Van Huyen, Hanoi, Vietnam
[6] VAST, High Technol Dev Ctr HTD, 18 Hoang Quoc Viet, Hanoi, Vietnam
关键词
rGO; PEDOT; electrochemical sensors; paracetamol; GRAPHENE; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); SUPERCAPACITORS; INTERFACE;
D O I
10.1088/2043-6254/ab0883
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This paper develops a novel and convenient approach to deposit poly(3,4-ethylenedioxythiophene)-reduced graphene oxide (PEDOT-rGO) hybrid film in aqueous solution through electrochemical process. The PEDOT-rGO film exhibited supperior charge transfer capability with charge transfer resistance of 1333 Omega.cm(-2) and standard transfer rate constant of 0.145 s(-1), which makes it a promising material for electrochemical sensing applications. The glassy carbon electrode modified with PEDOT-rGO showed good electrocatalytic performance towards acetaminophen with limit detection of 5.74 mu M, linear concentrations ranging from 10 to 60 mu M and sensitivity of 23.5 mu A.mu M-1.cm(-2). The use of acetaminophen sensor based on PEDOT-rGO in analysing Vietnamese traditional medicaments was demonstrated.
引用
收藏
页数:8
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共 36 条
  • [1] Applications of graphene in electrochemical sensing and biosensing
    Bahadir, Elif Burcu
    Sezginturk, Mustafa Kemal
    [J]. TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2016, 76 : 1 - 14
  • [2] Development of label-free electrochemical lactose biosensor based on graphene/poly(1,5-diaminonaphthalene) film
    Binh Hai Nguyen
    Binh Thanh Nguyen
    Hanh Van Vu
    Chuc Van Nguyen
    Dzung Tuan Nguyen
    Loc Thai Nguyen
    Thu Thi Vu
    Lam Dai Tran
    [J]. CURRENT APPLIED PHYSICS, 2016, 16 (02) : 135 - 140
  • [3] Brodie B.C., 1859, Philosophical Transactions of the Royal Society of London, V149, P249
  • [4] Electrochemical sensors based on carbon nanomaterials for acetaminophen detection: A review
    Cernat, Andreea
    Tertis, Mihaela
    Sandulescu, Robert
    Bedioui, Fethi
    Cristea, Alexandru
    Cristea, Cecilia
    [J]. ANALYTICA CHIMICA ACTA, 2015, 886 : 16 - 28
  • [5] One-step synthesis of graphene/polyaniline hybrids by in situ intercalation polymerization and their electromagnetic properties
    Chen, Xiangnan
    Meng, Fanchen
    Zhou, Zuowan
    Tian, Xin
    Shan, Liming
    Zhu, Shibu
    Xu, Xiaoling
    Jiang, Man
    Wang, Li
    Hui, David
    Wang, Yong
    Lu, Jun
    Gou, Jihua
    [J]. NANOSCALE, 2014, 6 (14) : 8140 - 8148
  • [6] Electrochemical deposition and characterization of poly(3,4-ethylenedioxythiophene) on neural microelectrode arrays
    Cui, XY
    Martin, DC
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2003, 89 (1-2) : 92 - 102
  • [7] PEDOT:PSS/graphene quantum dots films with enhanced thermoelectric properties via strong interfacial interaction and phase separation
    Du, Fei-Peng
    Cao, Nan-Nan
    Zhang, Yun-Fei
    Fu, Ping
    Wu, Yan-Guang
    Lin, Zhi-Dong
    Shi, Run
    Amini, Abbas
    Cheng, Chun
    [J]. SCIENTIFIC REPORTS, 2018, 8
  • [8] Detection of trace levels of organophosphate pesticides using an electronic tongue based on graphene hybrid nanocomposites
    Facure, Murilo H. M.
    Mercante, Luiza A.
    Mattoso, Luiz H. C.
    Correa, Daniel S.
    [J]. TALANTA, 2017, 167 : 59 - 66
  • [9] The rise of graphene
    Geim, A. K.
    Novoselov, K. S.
    [J]. NATURE MATERIALS, 2007, 6 (03) : 183 - 191
  • [10] Intercalation Polymerization Approach for Preparing Graphene/Polymer Composites
    Guo, Yifan
    Peng, Fuxi
    Wang, Huagao
    Huang, Fei
    Meng, Fanbin
    Hui, David
    Zhou, Zuowan
    [J]. POLYMERS, 2018, 10 (01)