Synthesis of 4-diphenylphosphanylmethyl- and 4-phenylthiomethyl-1,4-methano-11,11-dimethyl-1,2,3,4-tetrahydroacridine: new N-P and N-S camphor-derived chiral ligands for asymmetric catalysis

被引：15

作者：

Chelucci, Giorgio ^{[1
]}

Baldino, Salvatore ^{[1
]}

机构：

[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

来源：

TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 10期

关键词：

D O I：

10.1016/j.tetasy.2006.05.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new procedure has been developed for the preparation of camphor-annulated quinoline with different substituents on the 1-methyl group of the (+)-camphor backbone. Amongst them, two new N-P and N-S ligands, namely the 4-(diphenylphosphanylmethyl)- and 4-(phenylthiomethyl)-1,4-methano-11,11-dimethyl-1,2,3,4-tetrahydroacridine, have been employed in asymmetric palladium-catalyzed allylic substitution. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1529 / 1536

页数：8