ROMPgel reagents in parallel synthesis

被引:116
作者
Barrett, AGM [1 ]
Hopkins, BT [1 ]
Köbberling, J [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
关键词
D O I
10.1021/cr0103423
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ring-opening metathesis polymerization (ROMP) gel reagents in parallel synthesis were investigated. The use of ROMP in the preparation of surface-functionalized inorganic and organic supports for application in heterogeneous catalysis was also discussed. It was shown that ROMPgels were very useful supports for the immobilization of reagents and scavengers. ROMPgels swelled significantly in a variety of solvents, and their physical properties were finely tuned by the use of cross-linkers in their polymerization.
引用
收藏
页码:3301 / 3323
页数:23
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共 144 条
[41]  
BUCHMEISER MR, 1998, AM LAB SHELTON CONN, V30, P16
[42]   TETRAMETHYLFLUOROFORMAMIDINIUM HEXAFLUOROPHOSPHATE - A RAPID-ACTING PEPTIDE COUPLING REAGENT FOR SOLUTION AND SOLID-PHASE PEPTIDE-SYNTHESIS [J].
CARPINO, LA ;
EL-FAHAM, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (19) :5401-5402
[43]   1-HYDROXY-7-AZABENZOTRIAZOLE - AN EFFICIENT PEPTIDE COUPLING ADDITIVE [J].
CARPINO, LA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (10) :4397-4398
[44]  
CASTRO B, 1975, TETRAHEDRON LETT, P1219
[45]   Synthesis of a triphenylphosphine reagent on non-cross-linked polystyrene support: Application to the Staudinger/Aza-Wittig reaction [J].
Charette, AB ;
Boezio, AA ;
Janes, MK .
ORGANIC LETTERS, 2000, 2 (24) :3777-3779
[46]   IMPROVED FISCHER INDOLE REACTION FOR THE PREPARATION OF N,N-DIMETHYLTRYPTAMINES - SYNTHESIS OF L-695,894, A POTENT 5-HT1D RECEPTOR AGONIST [J].
CHEN, CY ;
SENANAYAKE, CH ;
BILL, TJ ;
LARSEN, RD ;
VERHOEVEN, TR ;
REIDER, PJ .
JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (13) :3738-3741
[47]   Selected highlights in the application of ion-exchangers as supports for reagents in organic synthesis [J].
Chesney, A .
GREEN CHEMISTRY, 1999, 1 (05) :209-219
[48]   A SIMPLIFIED PROCEDURE FOR PREPARING 3,5-DISUBSTITUTED-1,2,4-OXADIAZOLES BY REACTION OF AMIDOXIMES WITH ACYL CHLORIDES IN PYRIDINE SOLUTION [J].
CHIOU, S ;
SHINE, HJ .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1989, 26 (01) :125-128
[49]   SOME 5-UNSUBSTITUTED ACETYLENIC AND VINYLIC 1,2,4-OXADIAZOLES [J].
CLAISSE, JA ;
FOXTON, MW ;
GREGORY, GI ;
SHEPPARD, AH ;
TILEY, EP ;
WARBURTO.WK .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1973, (20) :2241-2249
[50]   Heterogeneous catalysis in liquid phase transformations of importance in the industrial preparation of fine chemicals [J].
Clark, JH ;
Macquarrie, DJ .
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 1997, 1 (02) :149-162