Chiral iron complex catalyzed enantioselective oxidation of racemic benzoins

被引：58

作者：

Muthupandi, Pandi ^{[1
]}

Alamsetti, Santosh Kumar ^{[1
]}

Sekar, Govindasamy ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 22期

关键词：

NONENZYMATIC KINETIC RESOLUTION; SECONDARY ALCOHOLS; MOLECULAR-OXYGEN; S(N)2 DISPLACEMENT; ALDOL REACTIONS; HYDROXY-GROUPS; CONDENSATION; ALDEHYDES; DERIVATIVES; HALOGENS;

D O I：

10.1039/b904021h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient, economic and environmentally friendly enantioselective oxidation of racemic benzoins (alpha-hydroxy ketones) catalyzed by a chiral iron complex has been developed using molecular oxygen as a terminal oxidant with good selectivity and excellent enantiomeric excess.

引用

页码：3288 / 3290

页数：3

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