Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

被引：519

作者：

Holmes, Michael ^{[1
]}

Schwartz, Leyah A. ^{[1
]}

Krische, Michael J. ^{[1
]}

机构：

[1] Univ Texas Austin, Dept Chem, Welch Hall A5300,105 East 24th St, Austin, TX 78712 USA

来源：

CHEMICAL REVIEWS | 2018年 / 118卷 / 12期

关键词：

ALDEHYDE OXIDATION LEVEL; FORMING TRANSFER HYDROGENATION; C-H FUNCTIONALIZATION; ENANTIOSELECTIVE ADDITION; CONJUGATED DIENES; BOND FORMATION; REVERSE PRENYLATION; STEREOSELECTIVE ALLYLATION; HOMOALLYLIC ALCOHOLS; ASYMMETRIC ADDITION;

D O I：

10.1021/acs.chemrev.8b00213

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-catalyzed reductive coupling has emerged as an alternative to the use of stoichiometric organometallic reagents in an increasingly diverse range of carbonyl and imine additions. In this review, the use of diene, allene, and enyne pronucleophiles in intermolecular carbonyl and imine reductive couplings are surveyed, along with related hydrogen autotransfer processes.

引用

页码：6026 / 6052

页数：27

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