A catalyst-free protocol for direct oxidative esterification of alcohols and aldehydes

被引：30

作者：

Rajbongshi, Kamal Krishna ^{[1
]}

Sarma, Marias Jyoti ^{[1
]}

Phukan, Prodeep ^{[1
]}

机构：

[1] Gauhati Univ, Dept Chem, Gauhati 781014, Assam, India

来源：

TETRAHEDRON LETTERS | 2014年 / 55卷 / 39期

关键词：

TsNBr2; Oxidation; Methyl esterification; Alcohol; Aldehyde; ACID METHYL-ESTER; AROMATIC-ALDEHYDES; FACILE GENERATION; CONVERSION; TRANSFORMATION; ANTIBACTERIAL; DERIVATIVES; DIOLS; WATER;

D O I：

10.1016/j.tetlet.2014.07.124

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A fast, simple, and efficient protocol for the direct conversion of alcohols and aldehydes to methyl ester has been developed using TsNBr2 without any catalyst. The one pot reaction proceeds in the presence of a base at room temperature in methanol, to produce the corresponding methyl ester in high yield within a short time. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：5358 / 5360

页数：3

共 61 条

[51] ACIDS AS DERIVATIVES OF ALDEHYDES PREPARED WITH SILVER OXIDES [J].

THOMASON, SC ;

KUBLER, DG .

JOURNAL OF CHEMICAL EDUCATION, 1968, 45 (08) :546-&

[52]

Tohma H, 2003, SYNLETT, P723

[53] Facile oxidation of aldehydes to acids and esters with oxone [J].

Travis, BR ;

Sivakumar, M ;

Hollist, GO ;

Borhan, B .

ORGANIC LETTERS, 2003, 5 (07) :1031-1034

[54] Facile and efficient gold-catalyzed aerobic oxidative esterification of activated alcohols [J].

Wang, Lianyue ;

Li, Jun ;

Dai, Wen ;

Lv, Ying ;

Zhang, Yi ;

Gao, Shuang .

GREEN CHEMISTRY, 2014, 16 (04) :2164-2173

[55] A General and Efficient Zinc-Catalyzed Oxidation of Benzyl Alcohols to Aldehydes and Esters [J].

Wu, Xiao-Feng .

CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (29) :8912-8915

[56] Iron-Catalyzed One-Pot Oxidative Esterification of Aldehydes [J].

Wu, Xiao-Feng ;

Darcelli, Christophe .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 2009 (08) :1144-1147

[57] Iridium-Catalyzed Oxidative Methyl Esterification of Primary Alcohols and Diols with Methanol [J].

Yamamoto, Nobuyuki ;

Obora, Yasushi ;

Ishii, Yasutaka .

JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (08) :2937-2941

[58] Preparation and properties of hyperbranched aromatic polyimides via polyamic acid methyl ester precursors [J].

Yamanaka, K ;

Jikei, M ;

Kakimoto, M .

MACROMOLECULES, 2000, 33 (19) :6937-6944

[59] Oxidative carboxylation of arylaldehydes with water by a sulfoxylalkyl-substituted N-heterocyclic carbene catalyst [J].

Yoshida, Masahiro ;

Katagiri, Yuki ;

Zhu, Wen-Bin ;

Shishido, Kozo .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2009, 7 (19) :4062-4066

[60] Copper-Catalyzed Methyl Esterification Reactions via C-C Bond Cleavage [J].

Zhu, Yan ;

Yan, Hong ;

Lu, Linhua ;

Liu, Defu ;

Ron, Guangwei ;

Mao, Jincheng .

JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (19) :9898-9905

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