A hydroquinone based palladium catalyst for room temperature nitro reduction in water

被引：24
作者：
Kumar, Alok [1 ]
Purkait, Kallol [1 ]
Dey, Suman Kr [1 ]
Sarkar, Amrita [1 ]
Mukherjee, Arindam [1 ]
机构：
[1] Indian Inst Sci Educ & Res Kolkata, Dept Chem Sci, Mohanpur 741246, India
来源：
RSC ADVANCES | 2014年 / 4卷 / 66期
关键词：
CROSS-COUPLING REACTIONS; SUPPORTED GOLD NANOPARTICLES; TRANSFER HYDROGENATION; SELECTIVE REDUCTION; AROMATIC-AMINES; CHEMOSELECTIVE REDUCTION; HYDRIDE AFFINITIES; MILD CONDITIONS; NITROARENES; BONDS;
D O I：
10.1039/c4ra06547f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hydroquinone based palladium complex [Pd(H2L)(Cl)(2)] (1), acts as an efficient room temperature catalyst for reduction of nitroarenes in water as solvent. 1 also acts as a tandem catalyst for Suzuki-Miyaura cross coupling in ethanol followed by reduction of nitroarenes in one pot with a loading of 0.25 mol% catalyst.
引用
收藏
页码：35233 / 35237
页数：5
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