Microporous structure of highly permeable additive silicon-containing polytricyclononenes

被引：22

作者：

Chapala, P. P. ^{[1
]}

Bermeshev, M. V. ^{[1
]}

Gavrilova, N. N. ^{[2
]}

机构：

[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Leninskii Pr 29, Moscow 119991, Russia

[2] Mendeleev Univ Chem Technol Russia, Miusskaya Pl 9, Moscow 125047, Russia

来源：

POLYMER SCIENCE SERIES A | 2017年 / 59卷 / 01期

关键词：

GAS PERMEATION PROPERTIES; INTRINSIC MICROPOROSITY; SEPARATION MEMBRANES; TRANSPORT PROPERTIES; POLYMER; CATALYSTS; PIM-1; SI;

D O I：

10.1134/S0965545X17010035

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The porosity of a number of additive silicon-containing polytricyclononenes from the class of highly permeable polymers has been systematically studied for the first time by the method of low-temperature nitrogen adsorption/desorption. It has been shown that these polymers have a large specific surface area (390-790 m(2)/g) and are microporous. Dominant pore size ranges from 7 to 10 depending on the number of Me3Si groups in a monomer unit and their relative position.

引用

页码：143 / 148

页数：6

共 23 条

[1]

AVRAM M, 1968, REV ROUM CHIM, V13, P505

[2] Mobility of the spin probe TEMPO in glassy metathesis polymers with substituents containing flexible Si-O-Si groups [J].

Barashkova, I. I. ;

Bermeshev, M. V. ;

Wasserman, A. M. ;

Yampolskii, Yu. P. .

POLYMER SCIENCE SERIES A, 2015, 57 (03) :279-284

[3] Synthesis of High Molecular Weight Poly[3-{tris(trirnethylsiloxy)silyl}tricyclononenes-7] and Their Gas Permeation Properties [J].

Bermeshev, Maxim V. ;

Syromolotov, Aleksander V. ;

Gringolts, Maria L. ;

Starannikova, Ludmila E. ;

Yampolskii, Yurii P. ;

Finkelshtein, Eugene Sh. .

MACROMOLECULES, 2011, 44 (17) :6637-6640

[4] Gas permeation parameters and other physicochemical properties of a polymer of intrinsic microporosity: Polybenzodioxane PIM-1 [J].

Budd, Peter M. ;

McKeown, Neil B. ;

Ghanem, Bader S. ;

Msayib, Kadhum J. ;

Fritsch, Detlev ;

Starannikova, Ludmila ;

Belov, Nikolai ;

Sanfirova, Olga ;

Yampolskii, Yuri ;

Shantarovich, Victor .

JOURNAL OF MEMBRANE SCIENCE, 2008, 325 (02) :851-860

[5] Gas separation membranes from polymers of intrinsic microporosity [J].

Budd, PM ;

Msayib, KJ ;

Tattershall, CE ;

Ghanem, BS ;

Reynolds, KJ ;

McKeown, NB ;

Fritsch, D .

JOURNAL OF MEMBRANE SCIENCE, 2005, 251 (1-2) :263-269

[6] Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials [J].

Budd, PM ;

Ghanem, BS ;

Makhseed, S ;

McKeown, NB ;

Msayib, KJ ;

Tattershall, CE .

CHEMICAL COMMUNICATIONS, 2004, (02) :230-231

[7] Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity [J].

Budd, PM ;

Elabas, ES ;

Ghanem, BS ;

Makhseed, S ;

McKeown, NB ;

Msayib, KJ ;

Tattershall, CE ;

Wang, D .

ADVANCED MATERIALS, 2004, 16 (05) :456-+

[8] Synthesis of tricyclononenes and tricyclononadienes containing MX3-groups (M=C, Si, Ge; X=Cl, Me) [J].

Bulgakov, B. A. ;

Bermeshev, M. V. ;

Demchuk, D. V. ;

Lakhtin, V. G. ;

Kazmin, A. G. ;

Finkelshtein, E. Sh. .

TETRAHEDRON, 2012, 68 (09) :2166-2171

[9] Gas-transport properties of new mixed matrix membranes based on addition poly(3-trimethylsilyltricyclononene-7) and substituted calixarenes [J].

Chapala, P. P. ;

Bermeshev, M. V. ;

Starannikova, L. E. ;

Shantarovich, V. P. ;

Gavrilova, N. N. ;

Avakyan, V. G. ;

Filatova, M. P. ;

Yampolskii, Yu. P. ;

Finkelshtein, E. Sh. .

JOURNAL OF MEMBRANE SCIENCE, 2015, 474 :83-91

[10] A Novel, Highly Gas-Permeable Polymer Representing a New Class of Silicon-Containing Polynorbornens As Efficient Membrane Materials [J].

Chapala, Pavel P. ;

Bermeshev, Maxim V. ;

Starannikova, Ludmila E. ;

Belov, Nikolay A. ;

Ryzhikh, Victoria E. ;

Shantarovich, Victor P. ;

Lakhin, Valentin G. ;

Gavrilova, Natalia N. ;

Yarnpolskii, Yuri P. ;

Finkelshtein, Eugene Sh. .

MACROMOLECULES, 2015, 48 (22) :8055-8061

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