ZnO nanorods array based field-effect transistor biosensor for phosphate detection

被引:93
作者
Ahmad, Rafiq [1 ]
Ahn, Min-Sang [1 ]
Hahn, Yoon-Bong [1 ]
机构
[1] Chonbuk Natl Univ, Nanomat Proc Res Ctr, Sch Semicond & Chem Engn, 567 Baekjedaero, Jeonju 54896, Jeollabuk, South Korea
基金
新加坡国家研究基金会;
关键词
ZnO nanorods; Field-effect transistor; Phosphate biosensor; Pyruvate oxidase; High sensitivity; INORGANIC-PHOSPHATE; PYRUVATE OXIDASE; NITRATE; SENSOR; ELECTRODES; POLYMER; NITRITE; SAMPLES; WATER; IONS;
D O I
10.1016/j.jcis.2017.03.069
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A promising field-effect transistor (FET) biosensor has been fabricated based on pyruvate oxidase (PyO) functionalized ZnO nanorods (ZnO NRs) array grown on seeded SiO2/Si substrate. The direct and vertically grown ZnO NRs on the seeded SiO2/Si substrate offers high surface area for enhanced PyO immobilization, which further helps to detect phosphate with higher specificity. Under optimum conditions, the fabricated FET biosensor provided a convenient method for phosphate detection with high sensitivity (80.57 mu A mM(-1) cm(-2)) in a wide-linear range (0.1 mu M-7.0 mM). Additionally, it also showed very low effect of electroactive species, stability and good reproducibility. Encouraging results suggest that this approach presents a promising method to be used for field measurements to detect phosphate. (C) 2017 Published by Elsevier Inc.
引用
收藏
页码:292 / 297
页数:6
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