Generation of allylic indium by hydroindation of 1,3-dienes and one-pot reaction with carbonyl compounds

被引：17
|
作者：
Hayashi, Naoki
Honda, Hiroyuki
Yasuda, Makoto
Shibata, Ikuya
Baba, Akio
机构：
[1] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan
[2] Osaka Univ, Res Ctr Environm Preservat, Suita, Osaka 5650871, Japan
来源：
ORGANIC LETTERS | 2006年 / 8卷 / 20期
关键词：
D O I：
10.1021/ol061797n
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A hydroindation of 1,3-dienes by dichloroindium hydride (HlnCl(2)) generates allylic indiums that react with carbonyl or imine moieties in a one-pot treatment. The former reaction proceeds in a radical manner, and the latter is ionic allylation. Moreover, both reactions require no additives such as radical initiators, Lewis acids, or transition metal catalysts.
引用
收藏
页码：4553 / 4556
页数：4
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