Manganese(II) Coordination Polymer with μ1,1-Azido Bridge: Synthesis, Crystal Structure, and Magnetic Properties

被引：2

作者：

Cheng, Jing ^{[1
]}

Zhang, Shu Quan ^{[2
]}

Luo, Jun Hua ^{[2
]}

Song, Cheng ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China

[2] Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys Fujian, Fuzhou 350002, Fujian, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 10期

基金：

中国国家自然科学基金;

关键词：

TETRANUCLEAR NICKEL(II) COMPLEXES; SINGLE-CHAIN MAGNET; AZIDO BRIDGES; COPPER(II); LIGANDS; MN; BEHAVIOR; SYSTEMS; SPIN; NI;

D O I：

10.1002/zaac.201400107

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The manganese(II) coordination polymer [Mn(2-Meimi)(2)(mu(1,1)-N-3)(2)](n)center dot nH(2)O (1) (Meimi = 2- methyl-imidazole) with mu(1,1)-N-3 (end-on, EO) bridge was synthesized by hydrothermal reaction of MnCl2, NaN3, and Meimi. It was characterized by elemental analysis, IR spectroscopy, powder XRD, and magnetic measurements. Single crystal X-ray analysis revealed that compound 1 features a one-dimensional (1D) catenated structure and the 1D chains are further connected by strong intermolecular hydrogen bonds to a 3D supramolecular framework. Variable-temperature magnetic susceptibility measurements revealed that compound 1 displays dominant ferromagnetic interactions through the mu(1,1)-N-3 (end-on, EO) bridging mode.

引用

页码：2053 / 2056

页数：4

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