Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

被引：22

作者：

Conte, Marco ^{[1
]}

Ma, Yun ^{[1
]}

Loyns, Colin ^{[2
]}

Price, Peter ^{[2
]}

Rippon, David ^{[2
]}

Chechik, Victor ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Nufarm Ltd, Bradford BD12 9EJ, W Yorkshire, England

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2009年 / 7卷 / 13期

基金：

英国工程与自然科学研究理事会;

关键词：

AUTOXIDATION; CONSUMPTION;

D O I：

10.1039/b905893a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Convolution-based fitting of EPR spectra makes it possible to simultaneously determine concentrations of TEMPO and oxygen in TEMPO-inhibited polymerisations and autoxidations; this method is useful for understanding the chemistry of inhibitor mixtures.

引用

页码：2685 / 2687

页数：3

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