Siloxane-capped amorphous nano-SiOx/graphite with improved dispersion ability and battery anode performance

被引:27
作者
Kim, Jong-Seon [1 ]
Cao Cuong Nguyen [1 ]
Kim, Hyun-Jin [1 ]
Song, Seung-Wan [1 ]
机构
[1] Chungnam Natl Univ, Dept Fine Chem Engn & Appl Chem, Taejon 305764, South Korea
关键词
FLUOROETHYLENE CARBONATE; CYCLING ABILITY; COMPOSITE ANODE; SILICON ANODE; LITHIUM; LI; STABILIZATION; STABILITY; SI; NANOCOMPOSITES;
D O I
10.1039/c3ra47476c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Siloxane-capped amorphous nano-SiOx/graphite was prepared by simple reduction and self-organization, and facile particle dispersion. 92% capacity retention of the composite anode is ascribed to effective accommodation of the volume change, and uniform distribution of SiOx on the graphite matrix.
引用
收藏
页码:12878 / 12881
页数:4
相关论文
共 33 条
[1]   Improving the Stability of Nanostructured Silicon Thin Film Lithium-Ion Battery Anodes through Their Controlled Oxidation [J].
Abel, Paul R. ;
Lin, Yong-Mao ;
Celio, Hugo ;
Heller, Adam ;
Mullins, C. Buddie .
ACS NANO, 2012, 6 (03) :2506-2516
[2]   Solution reduction synthesis of surface stabilized silicon nanoparticles [J].
Baldwin, RK ;
Pettigrew, KA ;
Ratai, E ;
Augustine, MP ;
Kauzlarich, SM .
CHEMICAL COMMUNICATIONS, 2002, (17) :1822-1823
[3]   Room temperature solution synthesis of alkyl-capped tetrahedral shaped silicon nanocrystals [J].
Baldwin, RK ;
Pettigrew, KA ;
Garno, JC ;
Power, PP ;
Liu, GY ;
Kauzlarich, SM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (07) :1150-1151
[4]   The electrochemical reaction of Li with amorphous Si-Sn alloys [J].
Beaulieu, LY ;
Hewitt, KC ;
Turner, RL ;
Bonakdarpour, A ;
Abdo, AA ;
Christensen, L ;
Eberman, KW ;
Krause, JL ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (02) :A149-A156
[5]   Colossal reversible volume changes in lithium alloys [J].
Beaulieu, LY ;
Eberman, KW ;
Turner, RL ;
Krause, LJ ;
Dahn, JR .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (09) :A137-A140
[6]   Roles of Oxygen and Interfacial Stabilization in Enhancing the Cycling Ability of Silicon Oxide Anodes for Rechargeable Lithium Batteries [J].
Cao Cuong Nguyen ;
Choi, Hyun ;
Song, Seung-Wan .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (06) :A906-A914
[7]   Combination of acid-resistor and -scavenger improves the SEI stability and cycling ability of tin-nickel battery anodes in LiPF6-containing electrolyte [J].
Choo, Myeong-Ho ;
Nguyen, Cao Cuong ;
Hong, Sukhyun ;
Kwon, Yo Han ;
Woo, Sang-Wook ;
Kim, Je Young ;
Song, Seung-Wan .
ELECTROCHIMICA ACTA, 2013, 112 :252-257
[8]   Amorphous Si/SiOx/SiO2 nanocomposites via facile scalable synthesis as anode materials for Li-ion batteries with long cycling life [J].
Dai, Fang ;
Yi, Ran ;
Gordin, Mikhail L. ;
Chen, Shuru ;
Wang, Donghai .
RSC ADVANCES, 2012, 2 (33) :12710-12713
[9]   Silicon and carbon based composite anodes for lithium ion batteries [J].
Datta, Moni Kanchan ;
Kumta, Prashant N. .
JOURNAL OF POWER SOURCES, 2006, 158 (01) :557-563
[10]  
Dhas NA, 1998, CHEM MATER, V10, P3278