Comparative Analysis of Physical Mechanisms of Detonation Initiation in HMX and in a Low-Sensitive Explosive (TATB)

被引:46
作者
Grebenkin, K. F. [1 ]
机构
[1] Russian Fed Nucl Ctr, Zababakhin Inst Tech Phys, Snezhinsk 456770, Russia
关键词
detonation; macrokinetic reaction rate; TATB; HMX; hot spots; initiation; shock sensitivity; SHOCK-WAVE SENSITIVITY; HOT-SPOTS; MODEL;
D O I
10.1007/s10573-009-0011-y
中图分类号
O414.1 [热力学];
学科分类号
摘要
Based on the concept of hot spots, the basic physical factors determining the macrokinetics of chemical reactions in heterogeneous crystalline explosives are estimated. The macrokinetics in plasticized TATB is shown to be basically determined by the velocity of combustion propagation from microscopic reaction spots (hot spots), whereas the macrokinetics in plasticized HMX is determined by the density of hot spots.
引用
收藏
页码:78 / 87
页数:10
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