An improved synthesis of [26-2H3]castasterone

被引：4
|
作者：
Zhabinskii, Vladimir N. [1 ]
Gulyakevich, Olga V. [1 ]
Kurman, Peter V. [1 ]
Shabunya, Polina S. [1 ]
Fatykhava, Svetlana A. [1 ]
Khripach, Vladimir A. [1 ]
机构：
[1] Natl Acad Sci Belarus, Inst Bioorgan Chem, Minsk 220141, BELARUS
来源：
JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS | 2015年 / 58卷 / 13-14期
关键词：
brassinosteroids; epicastasterone; castasterone; synthesis; deuterium; BIOSYNTHETIC PRECURSORS; BRASSINOSTEROIDS; BRASSINOLIDE; CASTASTERONE; 2,3-EPOXYBRASSINOSTEROIDS; REARRANGEMENTS; SEEDLINGS; STEROIDS; HORMONES; ANALOGS;
D O I：
10.1002/jlcr.3353
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Commercially available epicastasterone has been employed as a starting material for the preparation of [26-H-2(3)]castasterone. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids.
引用
收藏
页码：469 / 472
页数：4
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