Synthesis of cyclic acetals of acetylenic carbonyl compounds

被引：6

作者：

Golovanov, A. A. ^{[1
]}

Raskil'dina, G. Z. ^{[2
]}

Bekin, V. V. ^{[1
]}

Bunev, A. S. ^{[1
]}

Mikhailova, N. N. ^{[1
]}

Zlotskii, S. S. ^{[2
]}

机构：

[1] Togliatti State Univ, 14 Ul Belorusskaya, Tolyatti 445667, Russia

[2] Ufa State Petr Technol Univ, 1 Ul Kosmonavtov, Ufa 450000, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2016年 / 65卷 / 07期

基金：

俄罗斯科学基金会;

关键词：

acetylenes; acetals; aldehydes; diols; cyclocondensation;

D O I：

10.1007/s11172-016-1507-8

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A condensation of alpha-acetylenic carbonyl compounds and their acyclic acetals with 1,2-diols gave substituted 1,3-dioxacycloalkanes in up to 90% yields. 2,4-Disubstituted 1,3-dioxolanes were formed as mixtures of steric isomers, in which trans-forms predominated according to the B3LYP/6-311+G(2d,p) calculations.

引用

页码：1757 / 1760

页数：4

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