Dehydration of diethylene glycol by pervaporation using HybSi ceramic membranes

被引:11
作者
Akberov, R. R. [1 ]
Fazlyev, A. R. [2 ]
Klinov, A. V. [2 ]
Malygin, A. V. [2 ]
Farakhov, M. I. [1 ]
Maryakhina, V. A. [1 ]
Kirichenko, S. M. [1 ]
机构
[1] Ltd Liabil Co, Inzhekhim Engn Promot Ctr, Kazan, Tatarstan, Russia
[2] Kazan Natl Res Technol Univ, Kazan, Tatarstan, Russia
关键词
pervaporation dehydration of diethylene glycol; pervaporation; HybSi ceramic membranes; hybrid material; membrane processes; membrane technology; CONCENTRATION POLARIZATION; HYBRID;
D O I
10.1134/S0040579514030014
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The pervaporation dehydration of diethylene glycol using ceramic tubular membranes with a hydrophilic selective layer formed from HybSi material was experimentally studied. The experiments were carried out over the process temperature range of 70-90A degrees C at pressures in the permeate part of membrane unit in the range of 5-30 mm Hg and at diethylene glycol concentrations in the range of 93.5-99.8 wt %. Dependences of the membrane surface area required for the dehydration of diethylene glycol over a predetermined range of concentrations on productivity, process temperature, and vacuum were determined.
引用
收藏
页码:650 / 655
页数:6
相关论文
共 16 条
[1]   Acetalization reaction of ethanol with butyraldehyde coupled with pervaporation. Semi-batch pervaporation studies and resistance of HybSi® membranes to catalyst impacts [J].
Agirre, I. ;
Gueemez, M. B. ;
van Veen, H. M. ;
Motelica, A. ;
Vente, J. F. ;
Arias, P. L. .
JOURNAL OF MEMBRANE SCIENCE, 2011, 371 (1-2) :179-188
[2]  
Bekirov T.M., 1999, TEKHNOLOGIYA OBRABOT
[3]   High-performance hybrid pervaporation membranes with superior hydrothermal and acid stability [J].
Castricum, Hessel L. ;
Kreiter, Robert ;
van Veen, Henk M. ;
Blank, Dave H. A. ;
Vente, Jaap F. ;
ten Elshof, Johan E. .
JOURNAL OF MEMBRANE SCIENCE, 2008, 324 (1-2) :111-118
[4]   Hybrid ceramic nanosieves: stabilizing nanopores with organic links [J].
Castricum, Hessel L. ;
Sah, Ashima ;
Kreiter, Robert ;
Blank, Dave H. A. ;
Vente, Jaap F. ;
ten Elshof, Johan E. .
CHEMICAL COMMUNICATIONS, 2008, (09) :1103-1105
[5]  
DYMENT ON, 1976, GLIKOLI DRUGIE PROIZ
[6]  
Farakhov M.I., 2012, VESTN KAZAN TEKHNOL, P166
[7]  
Hwang S.T., 1975, MEMBRANES SEPARATION
[8]   Industrial state-of-the-art of pervaporation and vapour permeation in the western countries [J].
Jonquières, A ;
Clément, R ;
Lochon, P ;
Néel, J ;
Dresch, M ;
Chrétien, B .
JOURNAL OF MEMBRANE SCIENCE, 2002, 206 (1-2) :87-117
[9]   Dehydration of glycerin solution using pervaporation: HybSi and polydimethylsiloxane membranes [J].
Mah, Shee-Keat ;
Chai, Siang-Piao ;
Wu, Ta Yeong .
JOURNAL OF MEMBRANE SCIENCE, 2014, 450 :440-446
[10]   Hybrid of pervaporation and condensation-distillation crystallization: A new combined separation technology [J].
Myasnikov, SK ;
Uteshinsky, AD ;
Kulov, NN .
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2003, 37 (06) :527-532