Nickel-Catalyzed Deoxygenative Deuteration of Aryl Sulfamates

被引：19

作者：

Kuriyama, Masami ^{[1
]}

Kujirada, Shota ^{[1
]}

Tsukuda, Kotaro ^{[1
]}

Onomura, Osamu ^{[1
]}

机构：

[1] Nagasaki Univ, Grad Sch Biomed Sci, 1-14 Bunkyo Machi, Nagasaki 8528521, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2017年 / 359卷 / 06期

关键词：

Arenes; Deoxygenation; Deuteration; Nickel; Sulfamates; CROSS-COUPLING REACTIONS; ARENE H/D EXCHANGE; H BOND ACTIVATION; SELECTIVE DEUTERATION; PHENOL DERIVATIVES; ROOM-TEMPERATURE; DECARBOXYLATIVE DEUTERATION; HETEROARYL MESYLATES; GRIGNARD-REAGENTS; CARBOXYLIC-ACIDS;

D O I：

10.1002/adsc.201601105

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The nickel-catalyzed deoxygenative deuteration of aryl/heteroaryl sulfamates has been developed, and the effective incorporation of deuterium into a variety of aromatic compounds was achieved with sufficient catalytic efficiency and high deuteration degree. This process tolerated reducible functional moieties and heterocyclic structures. Additionally, a double introduction of deuterium also successfully gave a desired product with a high yield and deuterium content.

引用

页码：1043 / 1048

页数：6

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