Solubilities of 5,10,15,20-tetrakis(4-chlorophenyl) porphyrin manganese(III) chloride in N,N-dimethylformamide plus water mixtures

被引：5
|
作者：
Li, Chunlin [1 ]
Wang, Qinbo [1 ]
Shen, Binwei [2 ]
Xiong, Zhenhua [2 ]
Chen, Chuxiong [2 ]
机构：
[1] Hunan Univ, Dept Chem Engn, Changsha 410082, Hunan, Peoples R China
[2] Zhejiang Shuyang Chem Co Ltd, Quzhou 312402, Zhejiang, Peoples R China
来源：
FLUID PHASE EQUILIBRIA | 2014年 / 380卷
关键词：
Solubility; Experimental measurements; Modified Apelblat's correlation; N; N-dimethylformamide; Water; 5,10,15,20-Tetrakis(4-chlorophenyl) porphyrin manganese(III) chloride; ADIPIC ACID; OXIDATION; CYCLOHEXANE; LIGAND;
D O I：
10.1016/j.fluid.2014.08.006
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The solubility of 5,10,15,20-tetrakis(4-chlorophenyl) porphyrin manganese(III) chloride (abbreviated in p-CITPPMnCI) in N,N-dimethylformamide (abbreviated in DMF) + water solvent mixtures at 293.2-353.2 K were measured. The effects of mass fraction of DMF in the solvent mixtures at 1.00-0.80 on the solubility were studied. The results show that the solubility decreases with the decreasing mass fraction of DMF at constant temperature, and increase with the increasing temperature at constant solvent composition. The experimental data were correlated with Apelblat equation, and the solubilities calculated by the model were in good agreement with experimental observations. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：128 / 131
页数：4
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