Homologation of allylic alcohols. An approach to cyclic and acyclic polyoxygenated compounds

被引：40

作者：

Davoille, RJ ^{[1
]}

Rutherford, DT ^{[1
]}

Christie, SDR ^{[1
]}

机构：

[1] Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 08期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0040-4039(99)02263-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The combination of the Sharpless asymmetric epoxidation reaction with a sulfur ylide mediated synthesis of allylic alcohols from epoxides provides a powerful iterative process for the production of polyoxygenated compounds. The alkene installed in the sulfur ylide reaction has also been used in a number of ring closing metathesis reactions to produce highly oxygenated cyclic compounds. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1255 / 1259

页数：5

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