Reaction of N-Methylimidazole and Dimethyl Acetylenedicarboxylate in the Presence of N-Phenyl Carbamate under Solvent-free Conditions

被引：2
|
作者：
Hajinasiri, Rahimeh [1 ]
Khajavi, Halimeh Khatoon [1 ]
机构：
[1] Islamic Azad Univ, Qaemshahr Branch, Dept Chem, Qaemshahr, Iran
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2014年 / 69卷 / 04期
关键词：
N-Methylimidazole; Solvent-free; N-Phenylcarbamate 1,2,3-Functionalized Imidazoles;
D O I：
10.5560/ZNB.2014-3318
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An efficient synthesis of 1,2,3-functionalized imidazoles and dimethyl-2-[(alkoxycarbonyl)-anilino]-2-butenedioate derivatives via one-pot reactions between N-methylimidazole, dimethyl acetylenedicarboxylate and N-phenylcarbamates under solvent-free conditions is described. The mild reaction conditions and good yields exhibit the synthetic advantage of this method.
引用
收藏
页码：439 / 443
页数：5
相关论文
共 50 条
  • [31] Reaction Between Dimethyl Acetylenedicarboxylate and Phenols in the Presence of Dipotassium Hydrogen Phosphate in Solvent-Free Conditions: An Efficient Environment-Friendly Method for the Synthesis of Aryl Vinyl Ethers
    Ramazani, A.
    Safari, A.
    Noshiranzadeh, N.
    SCIENTIA IRANICA TRANSACTION C-CHEMISTRY AND CHEMICAL ENGINEERING, 2009, 16 (01): : 7 - 11
  • [32] Phthalimide-N-sulfonic acid: a new and efficient organocatalyst for the Biginelli reaction under solvent-free conditions
    Kiyani, Hamzeh
    Ghiasi, Maryam
    RESEARCH ON CHEMICAL INTERMEDIATES, 2015, 41 (09) : 6635 - 6648
  • [33] Phthalimide-N-sulfonic acid: a new and efficient organocatalyst for the Biginelli reaction under solvent-free conditions
    Hamzeh Kiyani
    Maryam Ghiasi
    Research on Chemical Intermediates, 2015, 41 : 6635 - 6648
  • [34] Reaction between dimethyl acetylenedicarboxylate and phenols in the presence of dipotassium hydrogen phosphate in solvent-free conditions: An efficient environment-friendly method for the synthesis of aryl vinyl ethers
    Department of Chemistry, Zanjan University, P.O Box 45195313, Zanjan, Iran
    Sci. Iran., 2009, 1 C (7-11):
  • [35] Catalytic performance of supported PbO catalysts for synthesis of methyl N-phenyl carbamate from aniline and dimethyl carbonate
    Kang Wukui
    Kang Tao
    Ma Fei
    Zhao Yongfeng
    Cui Lili
    Yao Jie
    Wang Gongying
    CHINESE JOURNAL OF CATALYSIS, 2007, 28 (01) : 5 - 9
  • [36] Catalytic stereoselective Mannich reaction under solvent-free conditions
    Azizi, Najmadin
    Baghi, Roya
    Batebi, Elham
    Bolourtchian, Seyed Mohammad
    COMPTES RENDUS CHIMIE, 2012, 15 (04) : 278 - 282
  • [37] A Practical Approach for the Transamidation of N,N-Dimethyl Amides with Primary Amines Promoted by Sodium tert-Butoxide under Solvent-Free Conditions
    Zhang, Rui
    Zhang, Jun-Chao
    Zhang, Wei-Yi
    He, Yu-Qing
    Cheng, Hua
    Chen, Cheng
    Gu, Yu-Cheng
    SYNTHESIS-STUTTGART, 2020, 52 (21): : 3286 - 3294
  • [38] A convenient and efficient synthesis of N-acylsulfonamides in the presence of silica phosphoric acid under heterogeneous and solvent-free conditions
    Massah, Ahmad Reza
    Dabagh, Mina
    Afshar, Maryam
    Momeni, Ahmad Reza
    Aliyan, Hamid
    Naghash, Hamid Javaherian
    TURKISH JOURNAL OF CHEMISTRY, 2007, 31 (06) : 611 - 616
  • [39] A novel non-phosgene approach to the synthesis of methyl N-phenyl carbamate by a reaction of methanol with phenylurea
    Wang, XK
    Yan, SR
    Li, ZH
    Fan, KN
    Kang, MQ
    Peng, SY
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2004, 21 (02) : 378 - 380
  • [40] Indium-Catalyzed N-Formylation of Amines under Solvent-Free Conditions
    Kim, Joong-Gon
    Jang, Doo Ok
    SYNLETT, 2010, (08) : 1231 - 1234
12345