Deoxy-liquefaction of three different species of macroalgae to high-quality liquid oil

被引:18
作者
Li, Jinhua [1 ]
Wang, Guoming [1 ]
Chen, Ming [1 ]
Li, Jiedong [1 ]
Yang, Yaoyao [1 ]
Zhu, Qiuyan [1 ]
Jiang, Xiaohuan [1 ]
Wang, Zonghua [1 ]
Liu, Haichao [2 ]
机构
[1] Qingdao Univ, Teachers Coll, Coll Chem Sci & Engn, Qingdao 266071, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
基金
中国国家自然科学基金;
关键词
Macroalgae; Deoxy-liquefaction; Liquid oil; CALORIC FUEL HCF; BIO-OIL; ENTEROMORPHA-PROLIFERA; PYROLYSIS; BIOMASS; ALGAE; CONVERSION; BLOOMS;
D O I
10.1016/j.biortech.2014.06.080
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Three species of macroalgae (Ulva lactuca, Laminaria japonica and Gelidium amansii) were converted into liquid oils via deoxy-liquefaction. The elemental analysis, FTIR and GC-MS results showed that the three liquid oils were all mainly composed of aromatics, phenols, alkanes and alkenes, other oxygen-containing compounds, and some nitrogen-containing compounds though there were some differences in terms of their types or contents due to the different constituents in the macroalgae feedstocks. The oxygen content was only 5.15-7.30% and the H/C molar ratio was up to 1.57-1.73. Accordingly, the HHV of the three oils were 42.50, 41.76 and 40.00 MJ/kg, respectively. The results suggested that U. lactuca, L. japonica and G. amansii have potential as biomass feedstock for fuel and chemicals and that deoxy-liquefaction technique may be an effective way to convert macroalgae into high-quality liquid oil. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:110 / 118
页数:9
相关论文
共 28 条
[1]   Hydrothermal liquefaction of the brown macro-alga Laminaria Saccharina: Effect of reaction conditions on product distribution and composition [J].
Anastasakis, K. ;
Ross, A. B. .
BIORESOURCE TECHNOLOGY, 2011, 102 (07) :4876-4883
[2]   The characteristics of bio-oil produced from the pyrolysis of three marine macroalgae [J].
Bae, Yoon Ju ;
Ryu, Changkook ;
Jeon, Jong-Ki ;
Park, Junhong ;
Suh, Dong Jin ;
Suh, Young-Woong ;
Chang, Daejun ;
Park, Young-Kwon .
BIORESOURCE TECHNOLOGY, 2011, 102 (03) :3512-3520
[3]   Recent advances in liquid biofuel production from algal feedstocks [J].
Daroch, Maurycy ;
Geng, Shu ;
Wang, Guangyi .
APPLIED ENERGY, 2013, 102 :1371-1381
[4]   Catalytic pyrolysis of microalgae and their three major components: Carbohydrates, proteins, and lipids [J].
Du, Zhenyi ;
Hu, Bing ;
Ma, Xiaochen ;
Cheng, Yanling ;
Liu, Yuhuan ;
Lin, Xiangyang ;
Wan, Yiqin ;
Lei, Hanwu ;
Chen, Paul ;
Ruan, Roger .
BIORESOURCE TECHNOLOGY, 2013, 130 :777-782
[5]   Direct conversion of sunflower shells to alkanes and aromatic compounds [J].
Guo, Shipeng ;
Wu, Libin ;
Wang, Chao ;
Li, Jinhua ;
Yang, Zhengyu .
ENERGY & FUELS, 2008, 22 (05) :3517-3522
[6]   Bio-oil production through pyrolysis of blue-green algae blooms (BGAB): Product distribution and bio-oil characterization [J].
Hu, Zhiquan ;
Zheng, Yang ;
Yan, Feng ;
Xiao, Bo ;
Liu, Shiming .
ENERGY, 2013, 52 :119-125
[7]   Micro and macroalgal biomass: A renewable source for bioethanol [J].
John, Rojan P. ;
Anisha, G. S. ;
Nampoothiri, K. Madhavan ;
Pandey, Ashok .
BIORESOURCE TECHNOLOGY, 2011, 102 (01) :186-193
[8]   Preparation and characteristics of bio-oil from the marine brown alga Sargassum patens C. Agardh [J].
Li, Demao ;
Chen, Limei ;
Xu, Dong ;
Zhang, Xiaowen ;
Ye, Naihao ;
Chen, Fangjian ;
Chen, Shulin .
BIORESOURCE TECHNOLOGY, 2012, 104 :737-742
[9]   Pyrolytic characteristics and kinetic studies of three kinds of red algae [J].
Li, Demao ;
Chen, Limei ;
Zhang, Xiaowen ;
Ye, Naihao ;
Xing, Fuguo .
BIOMASS & BIOENERGY, 2011, 35 (05) :1765-1772
[10]   Pyrolytic characteristics and kinetics of two brown algae and sodium alginate [J].
Li, Demao ;
Chen, Limei ;
Yi, Xiujie ;
Zhang, Xiaowen ;
Ye, Naihao .
BIORESOURCE TECHNOLOGY, 2010, 101 (18) :7131-7136