Full Characterization and Photoelectrochemical Behavior of Pyrene-fused Octaazadecacene and Tetraazaoctacene

被引：28

作者：

Wang, Zilong ^{[1
]}

Miao, Jianwei ^{[2
]}

Long, Guankui ^{[1
]}

Gu, Peiyang ^{[1
]}

Li, Junbo ^{[1
]}

Aratani, Naoki ^{[3
]}

Yamada, Hiroko ^{[3
]}

Liu, Bin ^{[2
]}

Zhang, Qichun ^{[1
,4
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[2] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore

[3] Nara Inst Sci & Technol, Grad Sch Mat Sci, Ikoma 6300192, Japan

[4] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 04期

关键词：

azaacenes; n-type semiconductors; octaazadecacene; organic electronics; photoelectrochemical behavior; tetraaazaoctacene; N-TYPE; LARGER ACENES; PHYSICAL-PROPERTIES; TRANSISTORS; STRATEGY; MEMORY; HETEROACENES; EFFICIENT; POLYMERS; DESIGN;

D O I：

10.1002/asia.201501276

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of large azaacenes is very important because of their great potential in organic electronics. In this report, we successfully synthesized and fully characterized two stable pyrene-fused large azaacenes: octaazadecacene and tetraazaoctacene through employing a relatively moderate aromatic unit pyrene as imbedded species in the backbone of azaacenes to ensure large conjugation and stability. The photoelectrochemical (PEC) studies indicate that both azaacenes display n-type semiconductor behavior.

引用

页码：482 / 485

页数：4

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