The hydrophobic effect and the excess free energy of solvation

被引：5
|
作者：
Shimizu, S [1 ]
机构：
[1] Univ York, Dept Chem, York Struct Biol Lab, York YO10 5YW, N Yorkshire, England
来源：
CHEMICAL PHYSICS LETTERS | 2004年 / 392卷 / 4-6期
关键词：
D O I：
10.1016/j.cplett.2004.04.124
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrophobic effect has been explained by the peculiar properties of liquid water. However, recent works by Marmur proposed a novel explanation: the hydrophobic effect is caused by the self-assembly of hydrophobic solutes driven by the theoretical upper bound of excess free energy. Here I show that this argument is erroneous, based upon a rigorous statistical mechanical analysis. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：456 / 459
页数：4
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