An improved 1,3-diene synthesis from alkyne and ethylene using cross-enyne metathesis

被引:81
作者
Tonogaki, K [1 ]
Mori, M [1 ]
机构
[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan
关键词
D O I
10.1016/S0040-4039(02)00215-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Synthesis of 1,3-diene from alkyne and ethylene (I atm) was improved using ruthenium carbene complex lb having heterocyclic carbene as a ligand. In this reaction, the heteroatom at the propargylic position was not required, although the reaction of alkyne with the first-generation ruthenium carbene complex la was affected by the substituent at the propargylic position. Various 1,3-dienes could be synthesized from alkynes and ethylene. (C) 2002 Published by Elsevier Science Ltd.
引用
收藏
页码:2235 / 2238
页数:4
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