Novel Preparation of N-Doped SnO2 Nanoparticles via Laser-Assisted Pyrolysis: Demonstration of Exceptional Lithium Storage Properties

被引:243
作者
Wang, Luyuan Paul [1 ,2 ,3 ]
Leconte, Yann [3 ]
Feng, Zhenxing [4 ]
Wei, Chao [1 ]
Zhao, Yi [1 ]
Ma, Qing [5 ]
Xu, Wenqian [6 ]
Bourrioux, Samantha [2 ,3 ]
Azais, Philippe [7 ]
Srinivasan, Madhavi [1 ,2 ]
Xu, Zhichuan J. [1 ,2 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[2] Nanyang Technol Univ, Energy Res Inst NTU ERI N, Interdisciplinary Grad Sch, Singapore 639798, Singapore
[3] CEA, IRAMIS, UMR NIMBE 3685, F-91191 Gif Sur Yvette, France
[4] Oregon State Univ, Sch Chem Biol & Environm Engn, Corvallis, OR 97331 USA
[5] Adv Photon Source, DND CAT, Northwestern Synchrotron Res Ctr, 9700 S Cass Ave, Argonne, IL 60439 USA
[6] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, 9700 S Cass Ave, Argonne, IL 60439 USA
[7] CEA, LITEN, F-38054 Grenoble, France
基金
新加坡国家研究基金会;
关键词
OPTICAL-PROPERTIES; ANODE MATERIALS; ELECTRONIC-STRUCTURE; ENERGY-STORAGE; ION BATTERIES; SITU TEM; CAPACITY; OXIDE; TIN; INTERCALATION;
D O I
10.1002/adma.201603286
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Laser pyrolyzed SnO2 nanoparticles with an option of nitrogen (N) doping are prepared using a cost-effective method. The electrochemical performance of N-doped samples is tested for the first time in Li-ion batteries where the sample with 3% of N-dopant exhibits optimum performance with a capacity of 522 mAh g(active material)(-1) that can be obtained at 10 A g(-1) (6.7C).
引用
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页数:12
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