Template Synthesis of Nitrogen-Doped Short Tubular Carbons with Big Inner Diameter and their Application in Electrochemical Sensing

被引:3
作者
Cheng, Rui [1 ]
Zou, Qiong [1 ]
Zhang, Xiaohua [1 ]
Xiao, Chunhui [1 ]
Sun, Longfei [1 ]
Chen, Jinhua [1 ]
机构
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
关键词
Nitrogen-doped short tubular carbons; Halloysite nanotubes; Electrochemistry; Template synthesis; OXYGEN REDUCTION REACTION; NANOTUBES; GRAPHENE; IMMOBILIZATION; PERFORMANCE; BIOSENSORS; OXIDATION; CATALYSTS; ELECTRODE; METHANOL;
D O I
10.5012/bkcs.2014.35.8.2423
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nitrogen-doped short tubular carbons (N-STCs) with big inner diameter have been successfully synthesized via carbonization of polydopamine (PDA) wrapped halloysite nanotubes (HNTs). The obtained N-STCs have average length of 0.3 mu m with big inner diameter (50 urn), thin wall (2-3 nm) and large surface area (776 m(2) g(-1)), and show excellent electrochemical properties. As an example in electrochemical applications, N-STCs were used to electrochemically detect hydrogen peroxide (H2O2) and glucose. The results showed that the N-STCs modified glassy carbon (N-STCs/GC) electrode had much better analytical performance (lower detection limit and wider linear range) compared to the acid-treated carbon nanotubes (AO-CNTs) based GC electrode. The unique structure endows N-STCs the enhanced electrochemical performance and promising applications in electrochemical sensing.
引用
收藏
页码:2423 / 2430
页数:8
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