Chemical analysis of outdoor silicone materials after electrical and environmental testing

被引：9

作者：

Krivda, A. ^{[1
]}

Greuter, F. ^{[1
]}

Rocks, J. ^{[1
]}

Kornmann, X. ^{[1
]}

Meier, P. ^{[1
]}

机构：

[1] ABB Switzerland, Corp Res, Baden, Switzerland

来源：

2006 ANNUAL REPORT CONFERENCE ON ELECTRICAL INSULATION AND DIELECTRIC PHENOMENA | 2006年

关键词：

D O I：

10.1109/CEIDP.2006.311951

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

In this work the results of electrical and environmental testing of outdoor silicone rubber insulating materials are presented. Degradation paths in silicone insulation were occasionally observed in the artificially accelerated and field tests. Chemical analysis of material in the degradation path has shown that the original material had transformed into the orthorhombic mullite Al6Si2O13. The formation of mullite in the degradation paths indicates that local surface temperatures during discharge activity on the surface may well be over 1200 degrees C degrees. Alumina trihydrate (ATH) filler was observed to be homogeneously distributed in the studied material. The filler had platelet-like form and was hexagonal in shape. The filler particles were several micrometers in size with submicrometer thickness. In addition to the ATH filler, occasional impurities such as NaCl and KCl salt crystals were observed in the bulk material. Soxhlet extraction has shown that tested high temperature vulcanised rubbers (HTV) contained about 2%w of low molecular weight (LMW) silicone species while liquid silicone rubber (LSR) contained about 4%w of LMW silicone.

引用

页码：389 / 392

页数：4

共 8 条

[1] Flashover of contaminated nonceramic outdoor insulators in a wet atmosphere
de la O, A
Gorur, RS
[J]. IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION, 1998, 5 (06) : 814 - 823
[2] KIM S, 1992, C EL INS DIEL PHEN V, P713
[3] KRIVDA A, 2001, C EL INS DIEL PHEN K, P572
[4] KRIVDA A, 2000, C EL INS DIEL PHEN V, P703
[5] KRIVDA A, 2001, 12 INT S HIGH VOLT E
[6] Polydimethylsiloxane and alumina trihydrate system subjected to dry-band discharges or high temperature - Part I: Chemical structure
Kumagai, S
Yoshimura, N
[J]. IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION, 2004, 11 (04) : 691 - 700
[7] von Hippel A. R, 1954, Dielectric Materials and Applications: Artech House on Demand
[8] Wypych G., 1999, Handbook of Fillers, V2nd

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