Synthesis of Calcium Hexaboride by Electrolysis of Molten Salt

被引:5
作者
Chernov, Yacov [1 ]
Filatov, Eugene [1 ,2 ]
Shurov, Nikolay [1 ]
Smolenski, Valery [1 ,3 ]
Tkachev, Nikolai [1 ]
机构
[1] RAS, UB, Inst High Temp Electrochem, Ekaterinburg 620137, Russia
[2] Ural Fed Univ, Ekaterinburg 620002, Russia
[3] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China
来源
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE | 2019年 / 50卷 / 04期
关键词
REDUCTION; MECHANISM;
D O I
10.1007/s11663-019-01626-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Formation of calcium hexaboride by means of electrodeposition of boron oxide in molten CaCl2 with additives of CaO and B2O3 was analyzed. It was shown that the hexaboride powder can be synthesized by electrolysis with a current output of more than 70pct and the process can be readily carried out continuously.
引用
收藏
页码:1745 / 1751
页数:7
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