TiO2 hybrid photocatalytic systems: impact of adsorption and photocatalytic performance

For the past 40 years, titanium dioxide (TiO2) nanomaterials have attracted immense attention because of their potential applications in the photodegradation of organic pollutants, photocatalytic water splitting for H-2 generation, and dye-sensitized solar cells. Despite the fact that the potential applications of TiO2 nanoparticles are ubiquitous, they are not problem free, examples include a large interfacial area that causes slow charge carrier transport, a wide optical band gap that leads to limited applications using solar light, and single-phase and nanoscales features that induce fast recombination of photo-reduced carriers. Therefore, this review highlights the development associated with the adsorption photocatalysis hybrid system for treating wastewater. The immobilization of TiO2 photocatalysts in metal oxide, carbon, and ceramic materials to form TiO2 hybrid systems could prevent the problem of particle recovery, adsorption capacity, and the separation process. Such hybrid systems require significant effort of optimizing the specific surface area-to-volume ratio of the supported photocatalysts with its photocatalytic activities.