Pd/C-catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes

被引：17

作者：

Igarashi, Masayasu ^{[1
]}

Kubo, Keiko ^{[1
]}

Matsumoto, Tomohiro ^{[1
]}

Sato, Kazuhiko ^{[1
]}

Ando, Wataru ^{[1
]}

Shimada, Shigeru ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

RSC ADVANCES | 2014年 / 4卷 / 37期

关键词：

DEHYDROCOUPLING POLYMERIZATION; NONHYDROLYTIC SYNTHESIS; TRIS(PENTAFLUOROPHENYL)BORANE; POLYSILOXANE; COPOLYMERS; COMPLEXES; POLYMERS; IODIDE;

D O I：

10.1039/c4ra02126f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new protocol for the nonhydrolytic synthesis of unsymmetrical siloxanes has been developed. The cross-coupling reaction of benzyloxysilanes with halosilanes catalyzed by Pd/C afforded various unsymmetrical siloxanes with co-production of benzyl halides.

引用

页码：19099 / 19102

页数：4

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