A novel high-stability Au(III)/Schiff-based catalyst for acetylene hydrochlorination reaction

被引：46
|
作者：
Huang, Chaofeng [1 ]
Zhu, Mingyuan [1 ,2 ]
Kang, Lihua [1 ,2 ]
Dai, Bin [1 ,2 ]
机构：
[1] Shihezi Univ, Sch Chem & Chem Engn, Shihezi 832000, Xinjiang, Peoples R China
[2] Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832000, Xinjiang, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2014年 / 54卷
基金：
中国国家自然科学基金;
关键词：
AuCl2(phen)]Cl; Acetylene hydrochlorination;
D O I：
10.1016/j.catcom.2014.05.024
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Herein, we reported on the application of an Au(III)/Schiff-based catalyst in acetylene hydrochlorination reaction. The [AuCl2(phen)]Cl catalyst exhibited excellent stability, and acetylene conversion was maintained at >90% after 40 h of operation. The excellent stability of the [AuCl2(phen)]Cl catalyst was attributed to the presence of the 1,10-phenanthroline ligand that partially inhibited the reduction of the Au3+ active component. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：61 / 65
页数：5
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