Rhodium-Catalyzed [2+2+2] Cycloaddition of Diynes with Carbodiimides and Carbon Dioxide under Ambient Conditions

被引：35
作者：
Ishii, Masahiro [1 ]
Mori, Fumiya [1 ]
Tanaka, Ken [1 ,2 ]
机构：
[1] Tokyo Univ Agr & Technol, Dept Appl Chem, Grad Sch Engn, Koganei, Tokyo 1848588, Japan
[2] ACT C, JST, Kawaguchi, Saitama 3320012, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 08期
基金：
日本科学技术振兴机构;
关键词：
cycloaddition; carbodiimides; carbon dioxide; diynes; rhodium; ENANTIOSELECTIVE SYNTHESIS; ALKENYL ISOCYANATES; NICKEL(0)-CATALYZED CYCLOADDITION; AROMATIC-COMPOUNDS; ALKYNES; NICKEL; CONSTRUCTION; COMPLEXES; CYCLOTRIMERIZATION; ALPHA; OMEGA-DIYNES;
D O I：
10.1002/chem.201304623
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
It has been established that a cationic rhodium(I)/H-8-binap complex is able to catalyze the [2+2+2] cycloaddition of diynes with carbodiimides and carbon dioxide under ambient conditions. Enantio- and/or regioselective variants of these reactions are also disclosed.
引用
收藏
页码：2169 / 2174
页数：6
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