Synthesis and Application of Pyrrole-Based PNP-Ir Complexes to Catalytic Transfer Dehydrogenation of Cyclooctane

被引：13

作者：

Nakayama, Shin ^{[1
]}

Morisako, Shogo ^{[2
]}

Yamashita, Makoto ^{[2
]}

机构：

[1] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, 1-13-27 Kasuga, Tokyo 1128551, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Mol & Macromol Chem, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648603, Japan

来源：

ORGANOMETALLICS | 2018年 / 37卷 / 08期

关键词：

PBP PINCER LIGAND; EFFECTIVE CORE POTENTIALS; B-H-ACTIVATION; THERMOCHEMICAL ALKANE DEHYDROGENATION; CRYSTAL-STRUCTURE DETERMINATION; IRIDIUM COMPLEXES; C-H; MOLECULAR CALCULATIONS; OXIDATIVE ADDITION; SELECTIVE REDUCTION;

D O I：

10.1021/acs.organomet.8b00072

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of Bu-t- and Pr-i-substituted PNP pincer Ir and Rh complexes with pyrrole-based core were synthesized and characterized. The structures of the obtained complexes were varied depending on the size of alkyl substituents and ligands other than PNP ligand. All of them exhibit low activity toward transfer dehydrogenation of cyclooctane.

引用

页码：1304 / 1313

页数：10

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