Mechanofluorochromic behavior of anthracene-based acylhydrazone derivatives

被引：3
|
作者：
Li, Zhiming [1 ,2 ]
Bai, Binglian [1 ]
Wei, Jue [1 ]
Wang, Haitao [2 ]
Chai, Qing [1 ]
Sun, Caijuan [2 ]
Li, Min [2 ]
机构：
[1] Jilin Univ, Coll Phys, Changchun 130012, Jilin, Peoples R China
[2] Jilin Univ, Minist Educ, Key Lab Automobile Mat JLU, Changchun 130012, Jilin, Peoples R China
来源：
TETRAHEDRON | 2018年 / 74卷 / 27期
关键词：
Anthracene-based derivatives; Mechanofluorochromic; Fluorescence; Aggregation; AGGREGATION-INDUCED EMISSION; MECHANOCHROMIC LUMINESCENCE; PHOTOLUMINESCENCE COLOR; LIQUID-CRYSTALS; SOLID-STATE; PIEZOFLUOROCHROMISM; ISOMERIZATION; LIGHT; WATER; BOND;
D O I：
10.1016/j.tet.2018.05.058
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Two anthracene-based derivatives, having one or two acylhydrazone branches attached on the anthracene, namely, asymmetrical AHP-1 and symmetrical AHBP-1 were designed. These compounds exhibited mechanofluorochromic behavior with the emission colors reversibly changing upon grinding and recrystallizing. The mechanofluorochromic mechanism was explored and ascribed to the crystalline-amorphous phase transformation. In addition, the red-shifted extent of fluorescent emission of the ground AHBP-1 samples was more than that of AHP-1. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3770 / 3775
页数：6
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