Palladium/Me3SiOTf-catalyzed bis-silylation of α,β-unsaturated carbonyl compounds without involving oxidative addition of disilane

被引：59

作者：

Ogoshi, S ^{[1
]}

Tomiyasu, S ^{[1
]}

Morita, M ^{[1
]}

Kurosawa, H ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 39期

关键词：

D O I：

10.1021/ja0272944

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalytic amount of Me3SiOTf and palladium(0), the addition of disilane to α,β-unsaturated carbonyl compounds proceeds under very mild conditions via η3-siloxyallylpalladium generated by the reaction of enone, enal, or aromatic aldehyde with palladium and Me3SiOTf. Copyright © 2002 American Chemical Society.

引用

页码：11598 / 11599

页数：2

共 22 条

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